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Which of the following atoms has the highest polarizability?


A) H
B) O
C) N
D) C
E) S

F) B) and E)
G) A) and E)

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There are 8 isomers that have the molecular formula C5H11Br.How many of these are tertiary alkyl bromides?


A) 0
B) 1
C) 2
D) 3
E) 8

F) B) and D)
G) None of the above

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B

Draw the most stable conformer of cis-1-ethyl-3-methylcyclohexane.

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Which of the following will have the lowest boiling point?


A) CH3Cl
B) CH4
C) CH2Cl2
D) CHCl3
E) CCl4

F) A) and C)
G) C) and D)

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Provide the systematic name of the compound shown. Provide the systematic name of the compound shown.

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6,7-dimethyl-3-octanol

Draw the Newman projection that represents the least stable conformation of 3,3-dimethylhexane viewed along the C3-C4 bond.

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Provide an acceptable name for the compound shown below. Provide an acceptable name for the compound shown below.

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5-ethyl-3,...

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Which of the molecules below has the higher boiling point? Briefly explain your choice. CH3CH2CH2OH or CH3CH2OCH3

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CH3CH2CH2OH has the hig...

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How many axial hydrogens are present in this molecule? How many axial hydrogens are present in this molecule?   A) 2 B) 3 C) 4 D) 5 E) 6


A) 2
B) 3
C) 4
D) 5
E) 6

F) C) and D)
G) A) and E)

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Provide an acceptable name for the alkane shown below. Provide an acceptable name for the alkane shown below.

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3-ethyl-4,...

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Provide an acceptable name for the alkane shown below. CH3CH2CH2CH2CH2CH3

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Provide the IUPAC name of the compound. Provide the IUPAC name of the compound.   A) N,N,1,1-tetramethylethanamine B) N,N-dimethyl-2-butanamine C) N,N,2-trimethyl-1-propanamine D) N,N,2-trimethylpropanamine E) N,N,2-trimethyl-2-propanamine


A) N,N,1,1-tetramethylethanamine
B) N,N-dimethyl-2-butanamine
C) N,N,2-trimethyl-1-propanamine
D) N,N,2-trimethylpropanamine
E) N,N,2-trimethyl-2-propanamine

F) A) and B)
G) B) and C)

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Which of the following is the staggered conformation for rotation about the C1-C2 bond in the following structure? Which of the following is the staggered conformation for rotation about the C<sub>1</sub>-C<sub>2</sub> bond in the following structure?   A) I B) II C) III D) IV E) V


A) I
B) II
C) III
D) IV
E) V

F) A) and C)
G) All of the above

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A

Draw the structure of N-ethyl-5-methyl-3-hexanamine.

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In the boat conformation of cyclohexane,the "flagpole" hydrogens are located on


A) the same carbon.
B) adjacent carbons.
C) C-1 and C-3.
D) C-1 and C-4.
E) none of the above.

F) B) and D)
G) B) and E)

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Explain why the molecule shown below has a lower boiling point than CH3CH2CH2CH3. Explain why the molecule shown below has a lower boiling point than CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>CH<sub>3</sub>.

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CH3CH2CH2CH3 has greater van der W...

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Arrange the following amines in order of increasing boiling point,lowest bp to highest bp: (CH3)2CHCH2CH2NH2,(CH3)2CHN(CH3)2,and (CH3)2CHCH2NHCH3.

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(CH3)2CHN(CH...

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Draw the most stable conformer of cis-1-isopropyl-2-methylcyclohexane.

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Define the term conformation.

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Conformations are different ar...

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Which of the following has the greatest van der Waal's interaction between molecules of the same kind?


A) Which of the following has the greatest van der Waal's interaction between molecules of the same kind? A)    B) CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>CH<sub>3</sub> C)    D) CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>CH<sub>3</sub> E)
B) CH3CH2CH2CH3
C) Which of the following has the greatest van der Waal's interaction between molecules of the same kind? A)    B) CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>CH<sub>3</sub> C)    D) CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>CH<sub>3</sub> E)
D) CH3CH2CH2CH2CH3
E) Which of the following has the greatest van der Waal's interaction between molecules of the same kind? A)    B) CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>CH<sub>3</sub> C)    D) CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>CH<sub>3</sub> E)

F) A) and B)
G) B) and D)

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