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Which of the following compounds is capable of hydrogen bonding?


A) CH4
B) H2CO
C) HCN
D) HCl
E) HNO2

F) C) and D)
G) B) and E)

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Identify the dominant intermolecular interaction or interactions that must be overcome when solid carbon dioxide (CO2)sublimes,when water (H2O)melts,and when acetone (CH3COCH3)evaporates.

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Carbon dioxide is nonpolar so ...

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Which of the following polar compounds is likely to have the highest boiling point?


A) CH3CH2CH3
B) CH3CH2OH
C) (CH3) 2CO
D) H2CO
E) CO

F) A) and B)
G) B) and D)

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The relative energies (strengths) of the intermolecular forces present in each of five different pure substances are shown in the figure below.Which substance has the highest melting point? The relative energies (strengths) of the intermolecular forces present in each of five different pure substances are shown in the figure below.Which substance has the highest melting point?   A) a B) b C) c D) d E) e


A) a
B) b
C) c
D) d
E) e

F) B) and C)
G) A) and B)

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Which of the following gases is likely to condense at the highest temperature (gas β†’\rightarrow liquid) ?


A) NH3
B) HCl
C) CH4
D) PH3
E) SiH4

F) B) and E)
G) C) and E)

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Stearic acid,a fatty acid commonly found in animal fat,has a condensed chemical formula of CH3(CH2) 16COOH.It is a common component of soaps and detergents.Which of the following statements is false?


A) The -COOH group would experience hydrogen bonding with water.
B) The long alkane "tail," CH3(CH2) 16-,is hydrophobic.
C) Stearic acid and water are probably miscible.
D) Stearic acid would probably dissolve in nonpolar solvents such as hexane,C6H14.
E) Stearic acid contains hydrophilic and hydrophobic regions.

F) B) and E)
G) A) and D)

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Which of the following statements regarding dispersion forces is false?


A) Electrons in one molecule can experience attractions to nuclei in a neighboring nonbonded molecule.
B) Temporary dipoles can arise when electrons are temporarily asymmetrically redistributed around the nucleus of an atom or within a bond.
C) As electron cloud size increases,the strength of dispersion forces increases.
D) The dipole moments associated with dispersion forces are long-lasting.
E) Temporary dipoles can induce dipoles in other particles.

F) B) and E)
G) None of the above

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Which of the following compounds would you predict can experience only dispersion forces?


A) ICl5
B) CH3Cl
C) PCl5
D) CH3OCH3
E) (CH3) 3N

F) A) and C)
G) A) and B)

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Which of the following would you predict has the highest polarizability?


A) CO2
B) CBr4
C) Cl2
D) CH4
E) CCl4

F) D) and E)
G) C) and E)

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Use the phase diagram to answer the following questions. a.What phase or phases are present at A,B,and C? b.What phase or phases are present along line E? c.What phase or phases are present at point D,and what is this point called? d.What is the name of point F? What phase or phases are present at higher pressures and temperatures? e.What physical quantity is on the x-axis? On the y-axis? Use the phase diagram to answer the following questions. a.What phase or phases are present at A,B,and C? b.What phase or phases are present along line E? c.What phase or phases are present at point D,and what is this point called? d.What is the name of point F? What phase or phases are present at higher pressures and temperatures? e.What physical quantity is on the x-axis? On the y-axis?

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a.In region A,the substance is solid; in...

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Molecular nitrogen (N2) interacts with water and is sparingly soluble in water due to _________


A) dispersion forces.
B) dipole-induced dipole forces.
C) ion-dipole forces.
D) hydrogen bonding.
E) dipole-dipole forces.

F) A) and C)
G) B) and C)

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Consider the phase diagram for a substance shown here.The solid phase is ________ than the liquid phase. Consider the phase diagram for a substance shown here.The solid phase is ________ than the liquid phase.   A) more dense B) less dense C) more massive D) less massive E) hotter


A) more dense
B) less dense
C) more massive
D) less massive
E) hotter

F) A) and E)
G) A) and D)

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Describe the similarity and the difference between sublimation and evaporation.

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In both sublimation and evapor...

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Which liquid,water or ethanol,would you expect to have the higher surface tension and viscosity? Explain.

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Water would have higher surface tension ...

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Which of the following diagrams best shows a set of polar molecules interacting through dipole-dipole interactions?


A)
Which of the following diagrams best shows a set of polar molecules interacting through dipole-dipole interactions? A)     B)     C)     D)     E) all of these
B)
Which of the following diagrams best shows a set of polar molecules interacting through dipole-dipole interactions? A)     B)     C)     D)     E) all of these
C)
Which of the following diagrams best shows a set of polar molecules interacting through dipole-dipole interactions? A)     B)     C)     D)     E) all of these
D)
Which of the following diagrams best shows a set of polar molecules interacting through dipole-dipole interactions? A)     B)     C)     D)     E) all of these
E) all of these

F) A) and D)
G) A) and C)

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Which of the following solvents could involve ion-dipole interactions with Na+?


A) benzene (C6H6)
B) carbon tetrachloride (CCl4)
C) chloroform (CHCl3)
D) cyclohexane (C6H12)
E) pentane (C5H12)

F) B) and E)
G) B) and C)

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The solubility of a compound may depend on many factors,including __________


A) solute-solvent interactions.
B) solute-solute interactions.
C) solvent-solvent interactions.
D) physical parameters such as temperature.
E) all of the items listed.

F) A) and E)
G) B) and C)

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Point d in the phase diagram below is the __________ Point d in the phase diagram below is the __________   A) critical point. B) triple point. C) transition point. D) normal freezing point. E) normal boiling point.


A) critical point.
B) triple point.
C) transition point.
D) normal freezing point.
E) normal boiling point.

F) D) and E)
G) A) and B)

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Why do the strengths of dispersion interactions generally increase with the molar mass of the compound?

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A molecule with the larger molar mass ha...

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Indicate whether the following pairs of molecules can interact via hydrogen bonding and give your reasoning. (a)CH3NH2 to CH3NH2; (b)CH3CH2OH to CH3OCH3; (c)CH3CH2CHO to CH3OCH3; and (d)(CH3)3N to CH3COCH3.

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Hydrogen bonding requires H directly bon...

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